See the dices are all about luck you use the to show what you would like to do
example if the opponent Gravios will use a Gravios Beam he or she will have to roll an instant death attack dice if he rolls 7 up to 12 you will get hit by it and die but you can roll the dice Evade if you can match or go higher than the enemy rolled you avoid it but if you roll lower you are dead
Shield is only for SnS users